Organic Chemicals

2,2-Di(tert-butylperoxy)butane

  • CAS:2167-23-9
  • purity:99%
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Top quality factory supply 2167-23-9 2,2-Di(tert-butylperoxy)butane at low price

  • Molecular Formula:C12H26O4
  • Molecular Weight:234.336
  • Appearance/Colour:(usually handled as a solution in mineral oil) 
  • Vapor Pressure:0.114mmHg at 25°C 
  • Melting Point:≥80 °C (SADT) 
  • Refractive Index:n20/D 1.445  
  • Boiling Point:227.818 °C at 760 mmHg 
  • Flash Point:70.497 °C 
  • PSA:36.92000 
  • Density:0.929 g/cm3 
  • LogP:3.60600 

2,2-Di(tert-butylperoxy)butane(Cas 2167-23-9) Usage

Reactivity Profile

Peroxides, such as 2,2-Di(tert-butylperoxy)butane, are good oxidizing agents. Organic compounds can ignite on contact with concentrated peroxides. Strongly reduced material such as sulfides, nitrides, and hydrides may react explosively with peroxides. There are few chemical classes that do not at least produce heat when mixed with peroxides. Many produce explosions or generate gases (toxic and nontoxic). Generally, dilute solutions of peroxides (<70%) are safe, but the presence of a catalyst (often a transition metal such as cobalt, iron, manganese, nickel, or vanadium) as an impurity may even then cause rapid decomposition, a buildup of heat, and even an explosion. Solutions of peroxides often become explosive when evaporated to dryness or near-dryness. Danger of explosion when dry. May explode from heat, shock, friction or contamination. May ignite combustibles (wood, paper, oil, clothing, etc.). May be ignited by heat, sparks or flames.

Flammability and Explosibility

Notclassified

InChI:InChI=1/C12H26O4/c1-9-12(8,15-13-10(2,3)4)16-14-11(5,6)7/h9H2,1-8H3

2167-23-9 Relevant articles

Lithographic printing method

-

, (2008/06/13)

A lithographic printing plate precursor ...

EFFECT OF STERIC FACTORS ON THE EQUILIBRIUM IN THE FORMATION OF TERT-BUTYLPEROXY KETALS FROM ALIPHATIC KETONES

Antonovskii, V. L.,Fedorova, E. V.,Shtivel', N. E.,Emelin, Yu. D.

, p. 704 - 706 (2007/10/02)

The equilibrium in the formation of tert...

Thermal decomposition of 2,2-bix(t-butyldioxy)alkanes

Suyama,Watanabe,Sawaki

, p. 716 - 720 (2007/10/02)

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2167-23-9 Process route

acetone
67-64-1

acetone

butanone
78-93-3

butanone

2,2-bis(tert-butylperoxy)butane
2167-23-9

2,2-bis(tert-butylperoxy)butane

Conditions
Conditions Yield
With sulfuric acid; at 10 ℃;
tert.-butylhydroperoxide
75-91-2

tert.-butylhydroperoxide

butanone
78-93-3

butanone

2,2-bis(tert-butylperoxy)butane
2167-23-9

2,2-bis(tert-butylperoxy)butane

Conditions
Conditions Yield
With sulfuric acid; water; In 1,4-dioxane; at 25 ℃; Equilibrium constant;
With hydrogenchloride;
With hydrogenchloride;

2167-23-9 Upstream products

  • 75-91-2
    75-91-2

    tert.-butylhydroperoxide

  • 78-93-3
    78-93-3

    butanone

  • 67-64-1
    67-64-1

    acetone

  • 7647-01-0
    7647-01-0

    hydrogenchloride

2167-23-9 Downstream products

  • 107-71-1
    107-71-1

    tert-butyl peroxyacetate

  • 1889-67-4
    1889-67-4

    dicumene

  • 3457-61-2
    3457-61-2

    tert-butyl cumyl peroxide

  • 67-64-1
    67-64-1

    acetone

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