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4,4'-DIBROMOOCTAFLUOROBIPHENYL

  • CAS:10386-84-2
  • purity:99%
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Reputable factory supply 4,4'-DIBROMOOCTAFLUOROBIPHENYL 10386-84-2 in stock with high standard

  • Molecular Formula:C12Br2F8
  • Molecular Weight:455.927
  • Appearance/Colour:white crystalline powder 
  • Melting Point:113-115 °C(lit.) 
  • Boiling Point:295.4 °C at 760 mmHg 
  • Flash Point:132.4 °C 
  • PSA:0.00000 
  • Density:2.065 g/cm3 
  • LogP:5.99140 

10386-84-2 Relevant articles

One-pot route to X-perfluoroarenes (X = Br, I) based on FeIII-assisted C-F functionalization and utilization of these arenes as building blocks for crystal engineering involving halogen bonding

Baykov, Sergey V.,Eliseeva, Anastasiya A.,Frontera, Antonio,Galmés, Bartomeu,Kukushkin, Vadim Yu.,Rozhkov, Anton V.

, p. 5908 - 5921 (2020)

Perfluorinated arenes (benzeneF derivati...

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Cohen,S.C. et al.

, p. 1 - 8 (1967)

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Synthesis of Bromochloropolyfluorobiphenyls Containing Bromine and Chlorine Atoms in the 4 and 4,4′ Positions

Maksimov, A. M.,Nikul’shin, P. V.,Platonov, V. E.

, p. 1316 - 1324 (2021/08/13)

Abstract: A new method for the synthesis...

Synthesis method of 2, 2', 3, 3', 5, 5', 6, 6'-octafluoro-4, 4'-dibromobiphenyl

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Paragraph 0012; 0027-0047, (2020/07/21)

The invention discloses a synthesis meth...

10386-84-2 Process route

1,4-dibromotetrafluorobenzene
344-03-6

1,4-dibromotetrafluorobenzene

4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl
10386-84-2

4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl

Conditions
Conditions Yield
1,4-dibromotetrafluorobenzene; With magnesium; ethylene dibromide; In tetrahydrofuran; at 20 ℃; for 6.25h; Inert atmosphere;
With (4-bromophenyl)magnesium bromide; copper(l) chloride; In tetrahydrofuran; at 10 - 15 ℃; for 3h; Reagent/catalyst; Solvent; Temperature;
92.3%
4′-bromooctafluoro-1,1′-biphenyl-4-thiol

4′-bromooctafluoro-1,1′-biphenyl-4-thiol

4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl
10386-84-2

4,4'-dibromo-2,3,5,6,2',3',5',6'-octafluoro-1,1'-biphenyl

Conditions
Conditions Yield
With bromine; at 218 - 220 ℃; for 24h; Heating; Sealed tube;
91%

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