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Perfect Factory Offer Excellent quality 2,5-DIMETHYLTETRAHYDROFURAN 1003-38-9 with Safe Shipping
- Molecular Formula: C6H12O
- Molecular Weight: 100.161
- Appearance/Colour: clear colorless liquid
- Vapor Pressure: 62.1mmHg at 25°C
- Melting Point: -45℃
- Refractive Index: n20/D 1.404(lit.)
- Boiling Point: 91 °C at 760 mmHg
- Flash Point: 26.7 °C
- PSA： 9.23000
- Density: 0.836 g/cm3
- LogP: 1.57380
2,5-DIMETHYLTETRAHYDROFURAN(Cas 1003-38-9) Usage
|
Synthesis Reference(s) |
Journal of the American Chemical Society, 72, p. 1593, 1950 DOI: 10.1021/ja01160a045 |
InChI:InChI=1/C6H12O/c1-5-3-4-6(2)7-5/h5-6H,3-4H2,1-2H3/t5-,6-/m0/s1
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It has only recently been established th...
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Cortese
, p. 1519 (1930)
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-
Bel'skii
, (1962)
-
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The diastereomers of 5-deuterio-2-hexano...
Generation of alkyl hypochlorites in oxidation of alcohols with carbon tetrachloride catalyzed by vanadium and manganese compounds
Khusnutdinov,Shchadneva,Baiguzina,Lavrentieva,Dzhemilev
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1003-38-9 Process route
-
-
2935-44-6
hexane-2,5-diol
-
-
1003-38-9
2,5-dimethyltetrahydrofuran
| Conditions | Yield |
|---|---|
|
Trichlorbutylstannan;
at 81 - 83 ℃;
for 4.3h;
|
100%
|
|
With
rhodium(III) iodide; hydrogen iodide; hydrogen;
In
water; toluene;
at 140 ℃;
for 4h;
under 15514.9 Torr;
|
100%
|
|
Al(III)-montmorillonite;
at 160 ℃;
for 0.666667h;
|
94%
|
|
Nafion-H;
at 135 ℃;
for 5h;
|
91%
|
|
With
aluminium phosphate aluminium oxide catalyst;
Heating;
|
80%
|
|
With
aluminum oxide;
at 220 - 250 ℃;
for 6h;
|
58%
|
|
With
sulfuric acid;
|
|
|
With
penthaethoxyphosphorane;
In
dichloromethane;
for 42h;
Ambient temperature;
|
69.3 % Chromat.
|
|
With
palladium/alumina; hydrogen;
at 200 ℃;
for 5h;
under 20702.1 Torr;
|
|
|
With
hydrogen;
In
neat (no solvent);
at 90 ℃;
for 5h;
under 15001.5 Torr;
|
> 99 %Chromat.
|
-
-
592-42-7
1,5-Hexadien
-
-
1003-38-9
2,5-dimethyltetrahydrofuran
| Conditions | Yield |
|---|---|
|
With
sulfuric acid;
|
|
|
With
sulfuric acid;
|
|
|
Multi-step reaction
with
2
steps
1: 65 percent / m-chloroperbenzoic acid / CHCl3
/ Ambient temperature
2: 1.) bromine; 2.) tributyltin hydride / 1.) dichloromethane, -78 deg C, 2 h.; 2.) ether, reflux, 24 h.
With
bromine; tri-n-butyl-tin hydride; 3-chloro-benzenecarboperoxoic acid;
In
chloroform;
|
1003-38-9 Upstream products
-
2935-44-6
hexane-2,5-diol
-
592-42-7
1,5-Hexadien
-
10353-53-4
1,2-epoxy-5-hexene
-
19056-49-6
2-methyl-5-iodomethyltetrahydrofuran
1003-38-9 Downstream products
-
100247-06-1
1-cyclohexyl-2,5-dimethyl-pyrrolidine
-
37035-03-3
N-Phenyl-2,5-dimethylpyrrolidine
-
18589-27-0
2-iodohexane
-
54462-67-8
meso -2,5-dibromo-hexane
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